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戊二醛交联对CCMC/PVA复合膜性能的影响
引用本文:鹿保鑫,王喜刚,周 睿,曹龙奎. 戊二醛交联对CCMC/PVA复合膜性能的影响[J]. 包装工程, 2011, 32(9): 1-4,19
作者姓名:鹿保鑫  王喜刚  周 睿  曹龙奎
作者单位:黑龙江八一农垦大学,大庆,163319;九三集团天津大豆科技有限公司,天津,300461;黑龙江八一农垦大学,大庆,163319;黑龙江省农产品加工工程技术研究中心,大庆,163319
基金项目:国家星火计划(2008GA670021)
摘    要:采用流延成膜工艺制备了CCMC/PVA共混复合膜,研究了戊二醛交联剂对复合膜的透光性能和力学性能的影响。结果表明:交联处理膜的致密性和机械性能显著提高;当戊二醛添加量为2%(质量分数),体系的pH为10,交联反应温度为85℃,交联时间为35 min时,复合膜的拉伸强度可达18.91 MPa,断裂伸长率为226%,透光率为75%。

关 键 词:戊二醛  交联羧甲基纤维素  复合膜  特性
收稿时间:2011-03-10
修稿时间:2011-05-10

Effect of Glutaraldehyde Crosslinking on Performance of CCMC/PVA Blend Films
LU Bao-xin,WANG Xi-gang,ZHOU Rui and CAO Long-kui. Effect of Glutaraldehyde Crosslinking on Performance of CCMC/PVA Blend Films[J]. Packaging Engineering, 2011, 32(9): 1-4,19
Authors:LU Bao-xin  WANG Xi-gang  ZHOU Rui  CAO Long-kui
Affiliation:1,3(1.Heilongjiang Bayi Agricultural University,Daqing 163319,China;2.Jiusan Group Tianjin Soya Science and Technology Co.,Ltd.,Tianjin 300461,China;3.Heilongjiang Farm Produce Processing Development Centre,Daqing 163319,China)
Abstract:CCMC/PVA blend film was prepared by solution mixing method.The effect of glutaric dialdehyde crosslinking agent on the hydrolytic resistance,light transmission and mechanical property of CCMC/ PVA complex film were studied.The results showed that the compactness,water resisting property and mechanical property of CCMC/PVA blend film increased remarkably by crosslinking treatment.The tensile strength was 18.91 MPa,elongation at break was 226%,luminousness was 75% when the amount of glutaric dialdehyde was 2%,pH was 10,crosslinking reaction temperature was 85 ℃,and reaction time was 35 min respectively.
Keywords:glutaric dialdehyde  cross-linked carboxymethyl cellulose  complex film  property
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