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废塑料与煤粉热解特性的研究
引用本文:郁庆瑶,林成城,张龙来,顾德仁,刘煜. 废塑料与煤粉热解特性的研究[J]. 宝钢技术, 2012, 0(1): 58-61
作者姓名:郁庆瑶  林成城  张龙来  顾德仁  刘煜
作者单位:宝山钢铁股份有限公司研究院,上海,201900;宝山钢铁股份有限公司炼铁厂,上海,200941
摘    要:分别将4种废塑料和煤粉置于非氧化性气氛中研究其热解特性。研究结果表明,在氮气中废塑料的裂解过程主要分为三个阶段:缓慢裂解—急速裂解—缓慢裂解至结束,煤粉的裂解过程比较平缓;最大裂解速度对应的温度,废塑料平均超过400℃,煤粉为900℃;终了裂解量,不同品种废塑料为85%~100%,而煤粉仅22%,两者差异极大;废塑料的完全裂解表观活化能是煤粉的6~10倍。

关 键 词:废塑料  煤粉  热解  裂解

Research on pyrolysis characteristics of waste plastics and coal powder
YU Qingyao , LIN Chengcheng , ZHANG Longlai , GU Deren , LIU Yu. Research on pyrolysis characteristics of waste plastics and coal powder[J]. Baosteel Technology, 2012, 0(1): 58-61
Authors:YU Qingyao    LIN Chengcheng    ZHANG Longlai    GU Deren    LIU Yu
Affiliation:1.Research Institute,Baoshan Iron & Steel Co.,Ltd.,Shanghai 201900,China; 2.Ironmaking Plant,Baoshan Iron & Steel Co.,Ltd.,Shanghai 200941,China)
Abstract:Four types of waste plastics and coal powder are placed in a non-oxidation atmosphere respectively for the purpose of studying their pyrolysis characteristics.The results show that under the condition of a nitrogen atmosphere,the waste plastics pyrolysis process can be mainly divided into three stages: slow cracking—fast cracking—slow cracking.The coal powder pyrolysis process is relatively gentle.To reach the maximum cracking speed,the average temperature of waste plastics is over 400℃,while the temperature of coal powder is about 900℃.As far as final cracking quantity is concerned,it is between 85%-100% for various waste plastics,while coal powder's is only 22%.There is great difference between waste plastics and coal powder.The apparent activation energy for waste plastics cracking is 6-10 times that of coal powder's.
Keywords:waste plastics  coal powder  pyrolysis  cracking
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