| 二苯乙二酮苯甲酰腙的合成、晶体结构及荧光性 |
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| 引用本文： | 杨滋渊,王亮,刘娟,郑长征. 二苯乙二酮苯甲酰腙的合成、晶体结构及荧光性[J]. 西北纺织工学院学报, 2011, 0(3): 357-361 |
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| 作者姓名： | 杨滋渊 王亮 刘娟 郑长征 |
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| 作者单位： | [1]陕西省人民医院药剂科,陕西西安710068 [2]西安工程大学环境与化学工程学院,陕西西安710048 |
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| 基金项目： | 陕西省自然科学基金项目（2009JM2012） |
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| 摘 要： | 由二苯乙二酮和苯甲酰肼通过缩合反应,合成新的酰腙化合物：二苯乙二酮苯甲酰腙.通过X射线单晶衍射和荧光光谱对该化合物进行晶体结构的表征.研究表明,该酰腙为三斜晶系,空间群为P-1,晶胞学数据：a=0.561 0（4）nm,α=99.868（9）,°b=1.028 5（8）nm,β=98.775（8）°,c=1.565 1（12）nm,=103.503（8）.°V=0.847 5（11）nm^3,Z=2,μ=0.087 mm^-1,Dc=1.350 mg/m^3,F（000）=364,R1=0.1461[I〉2sigma（I）],wR2=0.412 3（all data）.荧光光谱表明,该化合物的荧光性能较好,可以作为一种潜在的光活性材料.
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| 关 键 词： | 酰腙 晶体结构 X射线衍射 配体 荧光 |
Synthesis of 1,2-diphenyl ethanedionc benzohydrazide and its crystal structure and fluorescence properties |
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| YANG Zi-yuan,WANG Liang,LIU Juan,ZHENG Chang-zheng. Synthesis of 1,2-diphenyl ethanedionc benzohydrazide and its crystal structure and fluorescence properties[J]. Journal of Northwest Institute of Textile Science and Technology, 2011, 0(3): 357-361 |
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| Authors: | YANG Zi-yuan WANG Liang LIU Juan ZHENG Chang-zheng |
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| Affiliation: | 1.Pharmacy,Shaanxi Provincial People′s Hospital,Xi′an 710068,China;2.School of Environmental ＆ Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China) |
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| Abstract: | The 1,2-diphenyl ethanedionc benzohydrazide was synthesized by the reaction of 1,2-diphenyl ethanedionc and benzohydrazide.The crystal structure of the compound was characterized by X-ray diffraction and Fluorescence.It was assigned to triclinic crystal system,space group P-1,cell data：a=0.561 0（4）nm,α=99.868（9）°,b=1.028 5（8）nm,β=98.775（8）°,c=1.565 1（12）nm,γ=103.503（8）°,V=0.847 5（11）nm^3,Z=2,μ=0.087mm^-1,Dc=1.350mg/m^3,F（000）=364,R1=0.146 1[I〉2sigma（I）],wR2=0.412 3（all data）.Fluorescence spectra showed that the compound is a strong fluorescent substances,and can be used as a potential photoactive materials. |
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| Keywords: | hydrazone crystal structure X-Ray diffraction ligand fluorescence |
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