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Effects of Na, Cu, Ni and Co Modifications on the Activity and Characteristics of Rh/Al2O3 Catalysts for NO Reduction
Authors:Feng-Yim Chang  Jyh-Cherng Chen  Ming-Yen Wey
Affiliation:1. Department of Environmental Engineering, National Chung-Hsing University, 250 Kuo-Kuang Road, Taichung, 40227, Taiwan, ROC
2. Department of Environmental Engineering, Hung-kuang University, 34 Chung-Chie Road, Shalu, Taichung County, 43302, Taiwan, ROC
Abstract:This study used different metals to modify Rh/Al2O3 catalysts for NO reduction in a simulated waste incineration flue gas containing 6% O2. The characteristics of the modified catalysts were analyzed using BET, TEM and XRD. The results of the experiment reveal that Na addition can significantly affect the properties of Rh/Al2O3 catalysts on the BET surface area and Rh metal dispersion. Furthermore, Na addition was found to significantly enhance the NO conversion of Rh/Al2O3 at 250–350 °C. On the contrary, Cu, Ni, and Co addition was found to have slight suppression effects.
Keywords:
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