Enhanced Thermoelectric Performance of Rare-Earth-Free n-Type Oxide Perovskite Composite with Graphene Analogous 2D MXene

Here, the first experimental demonstration on the effect of incorporating new generation 2D material, MXene, on the thermoelectric performance of rare-earth-free oxide perovskite is reported. The charge localization phenomenon is predominant in the electron transport of doped SrTiO₃ perovskites, which deters from achieving a higher thermoelectric power factor in these oxides. In this work, it is shown that incorporating Ti₃C₂T_x MXene in a matrix of SrTi_0.85Nb_0.15O₃ (STN) facilitates the delocalization of electrons resulting in better than single-crystal-like electron mobility in polycrystalline composites. A 1851% increase in electrical conductivity and a 1000% enhancement in power factor are attained. Besides, anharmonicity caused by MXene in the STN matrix has led to enhanced Umklapp scattering giving rise to lower lattice thermal conductivity. Hence, 700% ZT enhancement is achieved in this composite. Further, a prototype of thermoelectric generator (TEG) using only n-type STN + MXene is fabricated and a power output of 38 mW is obtained, which is higher than the reported values for oxide TEG.