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A Metal Nanoparticle Thermistor with the Beta Value of 10 000 K |
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| Authors: | Xing Zhao Jiahui Guo Jingyu Wang Yong Yan |
| Affiliation: | 1. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190 P. R. China
School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, 710072 P. R. China;2. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190 P. R. China University of Chinese Academy of Sciences, Beijing, 100049 P. R. China;3. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190 P. R. China |
| Abstract: | The thermistor, typically made from metallic oxides, is a type of resistor whose electrical resistance is dependent on its temperature. Despite the wide usage, the limitations of ceramic thermistors become increasingly apparent as devices with improved performances are sought and as new applications emerge. Herein, a thermistor that is showed with a beta (B) value of 10 000 K can be made exclusively from metal nanoparticles functionalized with charged organic ligands. This B value is hard to achieve for ceramic devices, which is due to the increase of effective counterion concentration and its mobility upon thermal activation. Importantly, the performance of the nanoparticle thermistor is maintained when it is fabricated on a flexible substrate and experiences reversible bending. Demos of thermistor arrays for heat transfer, distribution, and comparison of their performance with commercial products are also demonstrated. Owing to the low temperature and simple casting process, conformably flexible characteristics, stable solid states, and ultra-high sensitivities, this device is expected to be practically used soon. |
| Keywords: | flexible ionic charges metal nanoparticles thermistors ultrahigh sensitivity |