| 十四元大环镍配合物[NiL](ClO4)2的合成及其晶体结构 |
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| 引用本文： | 刘捷,侯东兴. 十四元大环镍配合物[NiL](ClO4)2的合成及其晶体结构[J]. 河南工程学院学报(自然科学版), 2011, 23(1): 9-10 |
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| 作者姓名： | 刘捷 侯东兴 |
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| 作者单位： | 河南工业大学化学化工学院,河南郑州,450001 |
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| 摘 要： | 利用金属模板法合成了一个新的含对称噻吩基团十四元大环镍配合物[NiL](ClO4)2(L=3,10-二(2-噻吩乙基)-1,3,5,8,10,12-六氮十四元大环多胺,分子式为C20H34N6S2),采用溶剂挥发法培养单晶,通过X-单晶衍射手段对配合物进行了结构解析.
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| 关 键 词： | 大环镍(Ⅱ)配合物 合成 晶体结构 |
Synthesis and Crystal Structure of 14-member Macrocyclic Complex[NiL](ClO4)2 |
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| LIU Jie,HOU Dongxing. Synthesis and Crystal Structure of 14-member Macrocyclic Complex[NiL](ClO4)2[J]. Journal of Hennan Institute of Engineering(Natural Science Edition), 2011, 23(1): 9-10 |
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| Authors: | LIU Jie HOU Dongxing |
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| Affiliation: | (School of Chemistry and Chemical Engineering,Henan University of Technology,Zhengzhou 450001,China) |
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| Abstract: | A new macrocyclic complex [NiL](ClO4)2(L=3,10-bis(2-thiophenethyl)-1,3,5,8,10,12-hexaazacyclotetradecane,Molecular formula C20H34N6S2) containing two pendant symmetrical thiophene groups was synthesized by template synthesis method.The single crystal of [NiL](ClO4)2 was obtained through the method of evaporating solvent,and the crystal structure was analysised through X-ray single crystal diffraction. |
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| Keywords: | macrocyclic Ni(Ⅱ) macrocyclic complex synthesis crystal structure |
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