Synthesis,structure, and properties of new methacrylic derivatives of naphthalene‐2,3‐diol |
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Authors: | Barbara Gawdzik Beata Podkocielna Andrzej Bartnicki |
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Affiliation: | Barbara Gawdzik,Beata Podko?cielna,Andrzej Bartnicki |
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Abstract: | The synthesis of a new monomer, 2,3‐(2‐hydroxy‐3‐methacryloyloxypropoxy)naphthalene, and its copolymerization with divinylbenzene is presented. This monomer was obtained from naphthalene‐2,3‐diol in a two‐step synthesis. Copolymers in the form of porous microspheres were prepared by a suspension‐emulsion polymerization method. As pore‐forming diluents, toluene, 1‐decanol, benzyl alcohol, and their mixtures were used. In studies of their porous structure, two methods were used: the adsorption of nitrogen at low temperatures, which provided information about the porous structure of the material in a dry state, and inverse exclusion chromatography, which provided information about the porous structure of the polymer swollen by a good solvent. The obtained results suggest that the porous structures for the dry and swollen polymers were different. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1886–1895, 2006 |
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Keywords: | atomic force microscopy (AFM) copolymerization surfaces |
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