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Superparamagnetic flexible substrates based on submicron electrospun Estane® fibers containing MnZnFe?Ni nanoparticles
Authors:Pankaj Gupta  Ramazan Asmatulu  Rick Claus  Garth Wilkes
Abstract:Flexible, elastomeric, and superparamagnetic substrates were prepared by electrospinning a solution of elastomeric polyurethane containing ferrite nanoparticles (~14 nm) of Mn? Zn? Ni. The flexible mats were characterized in terms of fiber morphology and magnetic properties. Field emission scanning electron microscopy (FESEM) indicated that the diameter of these composite fibers was ~300–500 nm. Furthermore, the back‐scattered electron FESEM images indicated agglomeration of the nanoparticles at higher wt % (ca. 17–26 wt %) loading in the electrospun fibers. The induced specific magnetic saturation and the relative permeability were found to increase linearly with increasing wt % loading of the ferrite nanoparticles on the submicron electrospun fibers. A specific magnetic saturation of 1.7–6.3 emu/g at ambient conditions indicated superparamagnetic behavior of these composite electrospun substrates. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4935–4942, 2006
Keywords:electrospinning  fibers  polyurethane  ferrite nanoparticles  flexible substrates  superparamagnetic behavior
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