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Characterization of sulfonated poly(styrene–divinylbenzene) and poly(divinylbenzene) and its application as catalysts in esterification reaction
Authors:Fernanda M. B. Coutinho  Simone M. Rezende  Bluma G. Soares
Abstract:Polymeric supports based on divinylbenzene (DVB) were prepared by aqueous suspension polymerization in presence or absence of styrene (S), using toluene and n‐heptane as diluents of the monomers. Poly(S–DVB) and poly(DVB) were sulfonated with sulfuric acid in presence of 1,2‐dichloroethane. The influence of the morphological structure of the supports and as a consequence of the catalyst on the esterification reaction of acetic acid with n‐butanol was evaluated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3616–3627, 2006
Keywords:sulfonated poly(styrene–  divinylbenzene)  sulfonated poly(divinylbenzene)  catalyst activity  morphology characterization  sulfonic groups distribution
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