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Mass transfer study in a pulsed bed electrode - application to the electrodeposition of a poly(dibenzo-18-crown-6) film
Authors:N. Lebolay  J. F. Guilland  A. Ricard
Abstract:The polymerization of dibenzo-18-crown-6 has been carried out in an electrochemical reactor containing a granular electrode percolated by a pulsed solution. The influence of different parameters (pulse frequency, permanent flow velocity of the electrolytic solution, particle diameter and bed height) on the mass transfer has been studied. A correlation between the reduced mass transfer coefficient and the Strouhal number has been established. The maximum mass transfer coefficient and the maximum Strouhal number have been determined as a function of the Galilee number. The correlation predicts well the mass transfer coefficient over a larger range of the variables than previously achieved.
Keywords:Keywords: electrochemical reactor  polymerization  pulsed granular electrode  mass transfer  poly(dibenz0-18-crown-6)
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