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Al2O3/Cu-O composites fabricated by pressureless infiltration of paper-derived Al2O3 porous preforms
Authors:Stefan Pfeiffer  Hannes Lorenz  Zongwen Fu  Tobias Fey  Peter Greil  Nahum Travitzky
Affiliation:1. Department of Material Science, Institute of Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen, Germany;2. Tomsk Polytechnic University, Lenin Av. 30, Tomsk 634050, Russia
Abstract:Al2O3/Cu-O composites were fabricated from the paper-derived alumina matrix infiltrated with a Cu-3.2?wt% O alloy. Paper-derived alumina preforms with an open porosity ranging from ~ 14 to ~ 25?vol% were prepared by sintering of alumina-loaded preceramic papers at 1600?°C for 4?h. Pressureless infiltration at 1320?°C for 4?h of the preforms with Cu–O alloy resulted in the nearly dense materials with good mechanical and electrical properties, e.g. fracture toughness up to 6?MPa?m0.5, four-point-bending strength up to 342?MPa, Young's modulus up to 281?GPa and electrical conductivity up to 2?MS/m depending on the volume fraction of copper alloy in the composites. The technological capability of this approach was demonstrated using prototypes in various engineering fields fabricated by lamination, corrugating and Laminated Object Manufacturing (LOM) methods.
Keywords:Preceramic paper-derived ceramics  Pressureless metal infiltration  Microstructure  Mechanical properties  Additive manufacturing
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