| ATPU/环氧树脂固化物热稳定性的研究 |
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| 引用本文： | 陈文怡,官建国.ATPU/环氧树脂固化物热稳定性的研究[J].武汉理工大学学报,2007,29(1):37-39. |
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| 作者姓名： | 陈文怡 官建国 |
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| 作者单位： | 1. 武汉理工大学材料研究与测试中心,武汉,430070
2. 武汉理工大学材料复合新技术国家重点实验室,武汉,430070 |
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| 摘 要： | 采用热重法(TG-DTG)研究了2种含有柔性链和刚性结构单元的端胺基聚氨酯(ATPU-2和ATPU-1.5)对环氧树脂E-44固化物热稳定性特点和热分解动力学的影响。结果表明,固化剂ATPU-2与E-44固化物的热分解温度高于ATPU-1.5/E-44体系的固化物,ATPU-2/E-44固化物的分解残余量也高于ATPU-1.5/E-44体系。表明ATPU-2/E-44体系具有更好的热稳定性。固化反应动力学研究表明ATPU-2/E-44固化物的分解反应活化能高于ATPU-1.5/E-44体系。
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| 关 键 词： | 端胺基聚氨酯(ATPU) 环氧树脂(E-44) 热稳定性 热分解动力学 活化能 |
| 文章编号： | 1671-4431（2007）01-0037-03 |
| 修稿时间： | 2006-09-22 |
Research on the Curing Reaction Heat Resistance of ATPU/Epoxy Resin System |
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| CHEN Wen-yi,GUAN Jian-guo.Research on the Curing Reaction Heat Resistance of ATPU/Epoxy Resin System[J].Journal of Wuhan University of Technology,2007,29(1):37-39. |
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| Authors: | CHEN Wen-yi GUAN Jian-guo |
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| Affiliation: | 1, Center for Material Research and Analysis, Wuhan University of Technology, Wuhan 430070, China; 2. State Key Lab of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology, Wuhan 430070, China |
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| Abstract: | Thermogravimetry(TG-DTA) was used to study the heat resistance characteristics and curing heat decomposition kinetics of ATPU/Epoxy Resin System.Results showed that the decomposition temperature of the cured ATPU-2/E-44 was higher than that of ATPU-1.5/E-44.The calculation results of decomposition reaction showed that the cured system of ATPU-2/E-44 had better heat resistance,the reaction decomposition active energy of ATPU-2/E-44 system was higher than that of ATPU-1.5/E-44. |
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| Keywords: | amine-terminated polyurethane(ATPU) epoxy resin heat resistance heat decomposition kinetics active energy |
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