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AM/AA/AMPS/AMQC_(12)AB四元共聚物的合成及耐温抗盐性研究
引用本文:陈文全,贾慧,陈平. AM/AA/AMPS/AMQC_(12)AB四元共聚物的合成及耐温抗盐性研究[J]. 应用化工, 2014, 0(9): 1616-1619
作者姓名:陈文全  贾慧  陈平
作者单位:辽宁石油化工大学 化学与材料科学学院,辽宁 抚顺,113001
基金项目:辽宁省自然科学基金项目
摘    要:以AM、AA、AMPS、AMQC12AB为单体,VA-044为引发剂,合成了一种新型耐温抗盐的四元共聚物。考察了温度、体系pH、引发剂用量、AMPS含量、AMQC12AB含量对共聚物特性黏数的影响,并确定最佳反应条件。结果表明,比较适宜的反应条件为:聚合反应温度35℃,体系pH值7~9,引发剂用量为单体含量的0.5%,AMPS含量为单体总含量的10%,加入AMQC12AB含量为单体总含量的0.5%。聚合物测试表明,该聚合物具有良好的耐温抗盐性能。

关 键 词:三次采油  聚合物  耐温抗盐

Study on synthesis and properties of AM/AA/AMPS/AMQC12 AB tetrapolymer
CHEN Wen-quan,JIA Hui,CHEN Ping. Study on synthesis and properties of AM/AA/AMPS/AMQC12 AB tetrapolymer[J]. Applied chemical industry, 2014, 0(9): 1616-1619
Authors:CHEN Wen-quan  JIA Hui  CHEN Ping
Affiliation:(School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, China)
Abstract:A tetrapolymer was prepared by using raw material of AM,AA,AMPS and AMQC12 AB,with VA-044 as the initiator. The effect of the temperature,the amount of initiator and AMPS,AMQC12 AB a-mount and pH value on the intrinsic viscosity were investigated,and determine the optimal reaction condi-tions. The result showed that the optimum polymerization conditions were as follows:reaction temperature 35 ℃,pH was 7 ~ 9,10% for the weight fraction of AMPS,0. 5% for the weight fraction of initiator,0. 5% for the weight fraction of AMQC12 AB,with a alkalescent reaction system. Polymer tests showed that the tetrapolymer had a good tolerance to high salinity and high temperature.
Keywords:tertiary oil recovery  copolymer  heat-tolerant and salt-resistant performance
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