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新型低烟无卤阻燃电缆料的制备及表征
引用本文:张新,董振园,江斌斌.新型低烟无卤阻燃电缆料的制备及表征[J].塑料助剂,2013(4):39-43.
作者姓名:张新  董振园  江斌斌
作者单位:江苏亨通电力电缆有限公司,吴江,215234
摘    要:研究了以磷酸三甲苯酯(TCP)、水滑石(LDHs)、氢氧化铝(ATH)复配得到的复合阻燃剂对乙烯-醋酸乙烯酯共聚物(EVM:AV含量大于40%)性能的影响。分别通过氧指数、水平燃烧和拉伸性能测试考察了TCP/LDHs/ATH/EVM复合材料的阻燃性能和力学性能。结果表明,当TCP/LDHs/ATH/EVA为20/35/35/100(质量份数)时,复合材料的极限氧指数(LOI)达到35.2,阻燃级别为FH-1;断裂伸长率达到280%,拉伸强度达到11.0MPa。此复合材料可用于制造阻燃电缆。

关 键 词:乙烯-醋酸乙烯酯(EVM)  磷酸三甲苯酯  水滑石  氢氧化铝  无卤阻燃剂  电缆

Preparation and Characterization of A New Halogen-free Flame Retardant Cable
Zhang Xin , Dong Zhenyuan , Jiang Binbin.Preparation and Characterization of A New Halogen-free Flame Retardant Cable[J].Plastic Additives,2013(4):39-43.
Authors:Zhang Xin  Dong Zhenyuan  Jiang Binbin
Affiliation:Zhang Xin Dong Zhenyuan Jiang Binbin (Jiangsu Hengtong Wire Cable Co. ,Ltd. ,Wujiang,215234)
Abstract:The effect of the composite flame retardant synergistic system on the properties of ethylene-vinyl acetate(EVA) was studied. The system was compounded with trimethylphenyl phosphate(TCP) ,layered double hydroxides (LDHs) ,aluminum hydroxide (ATH) . The flame retardancy of phosphor-containing phenolic resins/LDHs/ATH/EVM composites was examined by using limiting oxygen index (LOI) ,horizontal burning (HB) test. The mechanical properties of TCP/ LDHs/ATH/ EVM composites were investigated by the mechanical measurement. The results indicated that when the mass ratio of TCP/LDHs/ATH/EVM is 20/35/35/100,the composite material keeps the FH 1 rating in horizontal burning test and the LOI value is 35. 2. The elongation percentage at break of TCP/LDHs/ATH/EVM composites is 240% ,and the tensile strength is 14. 0 MPa. This composite may be used to prepare the flame retardant cable.
Keywords:ethylene-vinyl acetate (EVM)  layered double hydroxides (LDHs)  aluminum hydroxide  halogen-free flame retardant  cable
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