Modeling of NC-AFM Imaging of Alkanethiols on the Au (111) Surface |
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Authors: | Maria L. Sushko Alexandros Kalampokidis Andrei Y. Gal Alexander L. Shluger |
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Affiliation: | Department of Physics and Astronomy and the London Centre for Nanotechnology, University College London, 17–19 Gordon Street, London WC1H 0AH, UK |
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Abstract: | We investigate the mechanisms of contrast formation in NC-AFM imaging of self-assembled monolayers of alkanethiols on the Au (111) surface. Comparing the potential models with implicit and explicit electrostatics, we demonstrate that, similar to the imaging of polar solid surfaces, the electrostatic interaction plays the central role in contrast formation. Careful comparison of several tip models showed that the model of a clean SiO2 tip gives the closest agreement with the experimental data. |
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