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Multisecular corrosion behaviour of low carbon steel in anoxic soils: Characterisation of corrosion system on archaeological artefacts
Authors:M Saheb  D Neff  P Dillmann  H Matthiesen  E Foy  L Bellot-Gurlet
Affiliation:1. Laboratoire Pierre Süe, UMR 9956 CEA/CNRS, bât. 637 CEA Saclay 91191 Gif-sur-Yvette (France);2. Laboratoire Pierre Süe, UMR 9956 CEA/CNRS, bât. 637 CEA Saclay 91191 Gif-sur-Yvette (France)

Institut de Recherche sur les Archéomatériaux, Laboratoire Métallurgies et Cultures, UMR 5060 CNRS (France);3. National Museum of Denmark, Department of Conservation, IC Modewegsvej, Brede, DK-2800 Lyngby (Denmark);4. LADIR UMR7075 CNRS/Université Pierre et Marie-Curie Paris 6, 2 rue H. Dunant, 94320 Thiais (France)

Abstract:In the context of the prediction of materials behaviour used in the nuclear waste storage, the understanding of iron corrosion mechanisms in anoxic environment is of great importance. Information can be obtained using complementary analytical tools. Interactions between burial soil and archaeological artefacts are studied by performing on site soil measurements. Moreover, archaeological artefacts are studied on transverse sections using a combination of microbeam techniques. The specific interest of this project lies in the study of ferrous thick corrosion layers formed in anoxic environments.
Keywords:anoxic soil  iron corrosion  on site measurements  Raman microspectroscopy  X-ray microdiffraction
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