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增容剂对纳米碳酸钙/聚丙烯/聚苯乙烯复合材料的等温结晶行为的影响
引用本文:黄勇平,麦堪成.增容剂对纳米碳酸钙/聚丙烯/聚苯乙烯复合材料的等温结晶行为的影响[J].绝缘材料,2006,39(3):32-35.
作者姓名:黄勇平  麦堪成
作者单位:中山大学,化学与化工学院,广东,广州,510275;中山大学,传播与设计学院,广东,广州,510275;中山大学,化学与化工学院,广东,广州,510275
基金项目:国家自然科学基金(50573094),广州市科技计划项目(2005Z3-D2131)
摘    要:采用Avrami方程研究了纳米碳酸钙/聚丙烯/聚苯乙烯(nano CaCO3/PP/PS)复合材料的等温结晶动力学。研究结果表明,nanoCaCO3填充PP/PS增容共混物复合材料的结晶速率明显高于nano CaCO3/PP/PS共混物复合材料的,而且结晶速率对结晶温度的依赖性显著降低,大分子相容剂对PP等温结晶行为的影响大于nano CaCO3。

关 键 词:聚丙烯  聚苯乙烯  纳米碳酸钙  共混物  等温结晶
文章编号:1009-9239(2006)03-0032-04
收稿时间:2006-02-19
修稿时间:2006-03-14

Effect of Compatibilizers on the Isothermal Crystallization Behavior of Nano CaCO3/PP/PS Composites
HUANG Yong-ping,MAI Kan-cheng.Effect of Compatibilizers on the Isothermal Crystallization Behavior of Nano CaCO3/PP/PS Composites[J].Insulating Materials,2006,39(3):32-35.
Authors:HUANG Yong-ping  MAI Kan-cheng
Abstract:The Avrami equation is used to investigate the isothermal crystallization behavior of composites of polypropylene/polystyrene(PP/PS) blend and compatibilized blend filled with nano CaCO_3.results show that the crystallization rate of composites of compatibilized PP/PS blend filled with nano CaCO_3 is higher than that of PP/PS blend filled with nano CaCO_3.The dependence of crystallization rate of composites of compatibilized PP/PS blend filled with nano CaCO_3 on crystallization temperatures is remarkably lower than that of composites of PP/PS blend filled with nano CaCO_3.The effect of macromolecular compatibilizers on isothermal crystallization behavior of PP is larger than that of nano CaCO_3.
Keywords:polypropylene  polystyrene  PP  PS  nano calcium carbonate  blend  isothermal crystallization
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