| 新型钯配合物合成及其光催化降解有机染料研究 |
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| 引用本文： | 仇雪,苏俊琪,高恩军.新型钯配合物合成及其光催化降解有机染料研究[J].当代化工,2016(12). |
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| 作者姓名： | 仇雪 苏俊琪 高恩军 |
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| 作者单位： | 沈阳化工大学配位化学研究室，辽宁省无机分子基化学重点实验室，辽宁沈阳 110142 |
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| 基金项目： | 国家自然科学基金项目，项目号21671138。 |
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| 摘 要： | 近年来,有机钯配合物被发现具有优异的催化性能因而被广泛应用于催化反应。一种新型钯配合物Pd(L)(Cl)2]已经通过常温挥发法合成出来(其中L代表1,3-双(二苯基膦基)丙烷配体),并通过元素分析,红外光谱和X射线单晶衍射仪进行了表征。在这个钯配合物中,氢键在结构组成中起到了很重要的作用。研究表明,该钯配合物具有良好的光催化降解有机染料活性。
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| 关 键 词： | 有机钯配合物 光催化降解 染料废水 |
Synthesis of a Novel Palladium Complex and Photocatalytic Degradation of Organic Dyes by the Palladium Complex |
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| Abstract: | In recent years, organic palladium complexes exhibit excellent catalytic performance and have been widely applied in organic catalytic reactions. A novel Pd(II) complex, Pd(L)(Cl)2],(L= 1,3-Bis(diphenylphosphino)propane), was synthesized under normal temperature volatilization method, and it was characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. The results show that hydrogen bond plays an important role in the construction of the Pd(II) complex; the Pd(II) complex has good catalytic degradation activity for organic dyes. |
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| Keywords: | palladium organic complexes photocatalytic degradation dye-containing wastewater |
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