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二甲苯用作锂离子电池过充保护的添加剂
引用本文:张千玉,秋沉沉,付延鲍,马晓华. 二甲苯用作锂离子电池过充保护的添加剂[J]. 电源技术, 2009, 33(9)
作者姓名:张千玉  秋沉沉  付延鲍  马晓华
作者单位:复旦大学材料科学系,上海,200433;复旦大学材料科学系,上海,200433;复旦大学材料科学系,上海,200433;复旦大学材料科学系,上海,200433
摘    要:二甲苯作为耐过充添加剂加入锂离子电池电解液中,实验发现,当电压为4.5 V(相对于Li/Li+)时,二甲苯开始在正极发生反应.并扩散在正极与隔膜之间.生成的物质阻止了Li+的传递,从而实现了过充电保护.

关 键 词:锂离子电池  过充保护  添加剂  二甲苯

Xylene as overcharge protection additive in lithium ion battery
ZHANG Qian-yu,QIU Chen-chen,FU Yan-bao,MA Xiao-hua. Xylene as overcharge protection additive in lithium ion battery[J]. Chinese Journal of Power Sources, 2009, 33(9)
Authors:ZHANG Qian-yu  QIU Chen-chen  FU Yan-bao  MA Xiao-hua
Affiliation:ZHANG Qian-yu,QIU Chen-chen,FU Yan-bao,MA Xiao-hua(Department of Materials Science,Fudan University,Shanghai 200433,China)
Abstract:Xylene as overcharging additive was added into Li-ion battery electrolyte.Xylene can electrochemically react at cathode from 4.5V(vs.Li/Li+)and diffuse between cathode and separator.The productor of polymer prevented the ion from transfering,therefore overcharge protection in lithium ion batteries can be achieved.
Keywords:lithium ion battery  overcharge protection  additive  xylene  
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