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活化硼氢化钠在有机合成中的应用
引用本文:戴利.活化硼氢化钠在有机合成中的应用[J].山东化工,2012,41(1):65-67.
作者姓名:戴利
作者单位:枣庄科技职业学院,山东滕州,277500
摘    要:介绍了有机合成反应中NaBH4与添加剂共同作用的反应,其中包括烯烃和炔烃的还原,羧酸的还原,氨基酸及其衍生物的还原,羧酸酯的还原,酰胺的还原,腈基的还原,酰氯的还原,硝基化合物的还原,醛酮的还原等。与LiAIH4的还原相比较,其反应条件更温和,反应过程更安全、易操控、易放大。

关 键 词:活化  NaBH4  有机合成

The Applications of the Activated Sodium Borohydride in Organic Synthesis
DAI Li.The Applications of the Activated Sodium Borohydride in Organic Synthesis[J].Shandong Chemical Industry,2012,41(1):65-67.
Authors:DAI Li
Affiliation:DAI Li(Zaozhuang Vocational College of Science and Technology,Tengzhou 277500,China)
Abstract:Introduced the applications of the activated sodium borohydride.It concluded reduction of alkene,alkyne,carboxylic acid,carboxylic acid ester,amide,nitrile group,acyl chloride,nitro group,aldehydes,ketones,amino acids as well as their derivatives.Comparing to the reduction of lithium aluminum hydride,it had milder reaction conditions,more secure reaction process and it was more easily controlled and amplified.
Keywords:activation  sodium borohydride  organic synthesis
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