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双官能团硫脲-胺催化剂催化不对称有机反应的研究进展
引用本文:史艳娜,孙传智,孙南. 双官能团硫脲-胺催化剂催化不对称有机反应的研究进展[J]. 山东化工, 2012, 41(2): 42-46
作者姓名:史艳娜  孙传智  孙南
作者单位:山东师范大学化学化工与材料科学学院,山东济南,250014
摘    要:双官能团硫脲-胺催化剂因在不对称催化反应中表现出的高效、高对映选择性而受到广泛关注,已成功应用于催化各种不对称有机反应中,本文简述了双官能团硫脲-胺催化剂在Michael加成、1,2加成以及Michael-type串联反应中应用的研究进展。

关 键 词:不对称催化反应  双官能团  有机反应  催化剂  硫脲  Michael加成    对映选择性

Rencent Advances in Asymmetric Organic Reactions Catalyzed by Bifunctional Amine- thioureas
SHI Yan-na,SUN Chuan-zhi,SUN Nan. Rencent Advances in Asymmetric Organic Reactions Catalyzed by Bifunctional Amine- thioureas[J]. Shandong Chemical Industry, 2012, 41(2): 42-46
Authors:SHI Yan-na  SUN Chuan-zhi  SUN Nan
Affiliation:(College of Chemistry,Chemical Engineering and Material Science, Shandong Normal University,Jinan 250014,China)
Abstract:Bifunctional amine-thiourea has received increasing attention as a highly efficient and enantioselective catalyst.It has been used for various reactions extensively.The applications of the catalyst in asymmetric Michael addition,1,2-addition,Michael-type cascade reaction were reviewed.
Keywords:asymmetric organocatalysis  bifunctional amine - thioureas  enantioselectivity
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