| 室温离子液体1-丁基-3-甲基咪唑六氟磷酸盐的合成研究 |
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| 引用本文： | 蔡月琴,彭延庆,宋恭华,黄菲菲,陆凤. 室温离子液体1-丁基-3-甲基咪唑六氟磷酸盐的合成研究[J]. 化学试剂, 2005, 27(1): 1-2 |
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| 作者姓名： | 蔡月琴 彭延庆 宋恭华 黄菲菲 陆凤 |
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| 作者单位： | 华东理工大学,药物研究所,上海,200237;华东理工大学,药物研究所,上海,200237;华东理工大学,药物研究所,上海,200237;华东理工大学,药物研究所,上海,200237;华东理工大学,药物研究所,上海,200237 |
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| 摘 要： | 由1-甲基咪唑和溴代正丁烷合成了中间体溴化1-丁基-3-甲基咪唑，讨论了温度和反应自身放热对此步反应的影响。中间体再经过阴离子交换，得到了标题化合物，收率为92％。产物的结构经IR和^1HNMR确认。
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| 关 键 词： | 1-丁基-3-甲基咪唑六氟磷酸盐 离子液体 合成 |
| 文章编号： | 0258-3283(2005)01-0001-02 |
| 修稿时间： | 2003-11-10 |
Study on the synthesis of room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate |
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| CAI Yue-qin,PENG Yan-qing,SONG Gong-Hua,HUANG Fei-fei,LU Feng. Study on the synthesis of room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate[J]. Chemical Reagents, 2005, 27(1): 1-2 |
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| Authors: | CAI Yue-qin PENG Yan-qing SONG Gong-Hua HUANG Fei-fei LU Feng |
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| Abstract: | The key intermediate, l-butyl-3-methylimidazolium bromide, was synthesized efficiently from 1-methylimidazole and l-bromobutane.The influence of temperature and reaction heat of itself on this reaction was also investigated. After anion exchanging, room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate was obtained in 92% yield.The structure of final product was confirmed by IR and 1HNMR spectral data. |
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| Keywords: | 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid synthesis |
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