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反应条件对水性聚氨酯预聚反应的影响
引用本文:李士杰,廖水姣,李建宗.反应条件对水性聚氨酯预聚反应的影响[J].粘接,2001,22(3):11-12,18.
作者姓名:李士杰  廖水姣  李建宗
作者单位:1. 武汉军事经济学院,
2. 华中农业大学,
3. 湖北大学,
摘    要:以TDI、N210、DMPA为基本原料,用丙酮法合成了稳定的聚氨酯乳液(WPU)。探讨了反应温度、溶剂、催化剂及用量对预聚反应的影响。结果表明:以丙酮为溶剂,以二月桂酸二丁基锡为催化剂(用量0.03%),反应温度80℃最为适宜。

关 键 词:预聚反应  预聚体  反应条件  水性聚氨酯

Effects of reaction conditions on prepolymerization of polyurethan emulsion
Li Shijie,Liao Shuijiao,Li Jianzong.Effects of reaction conditions on prepolymerization of polyurethan emulsion[J].Adhesion in China,2001,22(3):11-12,18.
Authors:Li Shijie  Liao Shuijiao  Li Jianzong
Affiliation:Li Shijie 1 Liao Shuijiao 2 Li Jianzong 3
Abstract:Stable waterborne polyurethane emulsion was prepared with N210,TDI,and DMPA by acetone process.Effects of reaction temperature,solvent,catalyst and its amount on prepolymerization was studied. Results showed that the most proper reaction temperature is about 80 ℃,when the prepolymerization reaction conducted in acetone solvent in the presence of dibutyltin dilaurate(0.03%) as the catalyst.
Keywords:Prepolymerization  Prepolymer  Reaction condition  
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