| 紫外光固化聚氨酯丙烯酸酯树脂的合成及流变行为研究 |
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| 引用本文： | 石翔,徐冬梅,匡敏,张可达.紫外光固化聚氨酯丙烯酸酯树脂的合成及流变行为研究[J].高分子材料科学与工程,2003,19(1):124-127. |
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| 作者姓名： | 石翔 徐冬梅 匡敏 张可达 |
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| 作者单位： | 苏州大学化学化工系,江苏,苏州,215006 |
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| 摘 要： | 采用不同方法合成紫外光固化聚氨酯丙烯酸酯，研究了原料配比，反应时间，加料顺序，催化剂等对其流变行为的影响，实验结果表明，在无催化剂的条件下，以丙烯酸羟乙酯先与异氰酸酯反应，后加蓖麻油的加料顺序可合成具有优良流动性和光固化性能的蓖麻油紫外光固化树脂。
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| 关 键 词： | 紫外光固化 聚氨酯丙烯酸酯树脂 合成 流变行为 研究 流变性 蓖麻油 |
| 文章编号： | 1000-7555(2003)01-0124-04 |
| 修稿时间： | 2001年2月1日 |
RHEOLOGICAL BEHAVIOR OF UV-CURABLE POLYURETHANE ACRYLATE RESIN |
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| SHI Xiang,XU Dong-mei,KUANG Min,ZHANG Ke-da.RHEOLOGICAL BEHAVIOR OF UV-CURABLE POLYURETHANE ACRYLATE RESIN[J].Polymer Materials Science & Engineering,2003,19(1):124-127. |
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| Authors: | SHI Xiang XU Dong-mei KUANG Min ZHANG Ke-da |
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| Abstract: | A series of UV-curable polyurethane acrylate polymers based on HDI, HEA and castor oil were synthesized. The effect of catalyst, the feeding order and material molar ratio and reaction time was studied respectively. It shows that a good fluidity resin can be prepared by using proper feeding way which HEA is reacted first with HDI and not adding catalyst. Thus, a UV-curable resin which has good fluidity and curable performance was synthesized by HDI, HEA and castor oil. |
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| Keywords: | polyurethane acrylate rheological property caster oil |
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