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A New Pyridine–Diphosphine Ligand for Self-Assembly of Coordination Polymers: Structure of a Polymeric Copper(I) Complex
Authors:Chang-Qiu Zhao  Michael C Jennings  Richard J Puddephatt
Affiliation:(1) Department of Chemistry, University of Western Ontario, London, Canada, N6A 5B7
Abstract:A new pyridine–diphosphine ligand, N-4-pyridyl-2,2-bis(diphenylphosphinomethyl)propionamide, 1, designed to form polymeric coordination compounds with potential for further self-assembly through amide hydrogen bonding is described. The complex with copper(I) iodide is shown to exist as a polymer with bridging ligands 1. Dedicated to Professor Didier Astruc, especially for his pioneering research on organometallic dendrimers.
Keywords:Polymer  Coordination  Copper  Self-assembly
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