A New Pyridine–Diphosphine Ligand for Self-Assembly of Coordination Polymers: Structure of a Polymeric Copper(I) Complex |
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Authors: | Chang-Qiu Zhao Michael C Jennings Richard J Puddephatt |
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Affiliation: | (1) Department of Chemistry, University of Western Ontario, London, Canada, N6A 5B7 |
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Abstract: | A new pyridine–diphosphine ligand, N-4-pyridyl-2,2-bis(diphenylphosphinomethyl)propionamide, 1, designed to form polymeric coordination compounds with potential for further self-assembly through amide hydrogen bonding
is described. The complex with copper(I) iodide is shown to exist as a polymer with bridging ligands 1.
Dedicated to Professor Didier Astruc, especially for his pioneering research on organometallic dendrimers. |
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Keywords: | Polymer Coordination Copper Self-assembly |
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