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| 甲基丙烯酸十八酯基油溶性聚合物反应过程的在线红外研究 | |
| 引用本文： | 韩涛,王晓云,于萍,代晓东,吕小博,李冰.甲基丙烯酸十八酯基油溶性聚合物反应过程的在线红外研究[J].山东大学学报(工学版),2011,41(2):144-148. |
| 作者姓名： | 韩涛 王晓云 于萍 代晓东 吕小博 李冰 |
| 作者单位： | 1. 山东大学化学与化工学院, 山东 济南 250061; 2. 山东省化工研究院, 山东 济南 250014; 3.中石油管道公司管道研究中心, 河北 廊坊 065000 |
| 基金项目： | 国家重点基础研究发展计划资助项目 |
| 摘 要： | 采用React IRTM4000在线红外检测装置和Auto-RC(reaction calorinleter)等温反应量热器对以甲基丙烯酸十八酯、马来酸酐、苯乙烯为原料的三元共聚过程进行了反应动力学研究和热量变化研究.研究结果表明,酯基、酸酐、苯环的吸光度随时间变化基本保持不变;C=C键断裂过程中吸光度随时间的变化情况... |
| 关 键 词： | 甲基丙烯酸十八酯-马来酸酐-苯乙烯三元共聚物 在线红外检测装置 等温反应量热 |
| 收稿时间： | 2010-09-02 |
React IRTMTM study of the synthesis of octadecyl methacrylate-based oil soluble polymer |
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| HAN Tao,WANG Xiao-yun,YU Ping,DAI Xiao-dong,Lu Xiao-bo,LI Bing.React IRTMTM study of the synthesis of octadecyl methacrylate-based oil soluble polymer[J].Journal of Shandong University of Technology,2011,41(2):144-148. | |
| Authors: | HAN Tao WANG Xiao-yun YU Ping DAI Xiao-dong Lu Xiao-bo LI Bing |
| Affiliation: | 1. School of Chemistry and Chemical Engineering, Jinan 250061, China; 2. Chemical Technology Academy of Shandong Province, Jinan 250014, China; 3 China National Petroleum Pipeline Corporation Pipeline Research Center, Langfang 065000, China |
| Abstract: | The kinetics of the copolymerizing process of octadecyl methacrylate,styrene and maleic anhydride were performed by using the react IR analytical system(React IRTM4000),and the heat flow derived from exothermic copolymerization was measured by an Auto-RC reaction calorimeter.The results showed that the absorbance of functional groups,i.e.ester,anhydride,and phenyl remained stable.The change of the absorbance with time corresponded to the ternary addition copolymerization control region when the C C bond was... |
| Keywords: | octadecyl methacrylate-styrene-maleic anhydride terpolymer the react IR system reaction calorimeter |
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