Fundamental Understanding and Facing Challenges in Structural Design of Porous Si-Based Anodes for Lithium-Ion Batteries |
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Authors: | Zhongling Cheng Hao Jiang Xinlin Zhang Fangyi Cheng Minghong Wu Haijiao Zhang |
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Affiliation: | 1. Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai, 200444 China;2. Shanghai Engineering Research Center of Hierarchical Nanomaterials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237 China;3. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071 China;4. School of Environmental and Chemical Engineering, Shanghai University, Shanghai, 200444 China |
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Abstract: | As one of the most electrochemical energy storage devices, lithium-ion batteries (LIBs) remain the workhorse of the energy market due to their unparalleled advantages. Remarkably, Si-based materials play a pivotal role in LIBs anodes owing to ultrahigh theoretical capacity of Si and rich natural resources. However, bulk silicon materials are difficult to meet the current commercial demand because of their low conductivity, sluggish reaction kinetics, and huge volume expansion. The construction of porous structures has been acknowledged as an effective way to solve the above issues. Herein, the delicate design of porous Si-based anode materials including synthetic strategies, the engineering of surface morphology and micro/nano-structure, and the regulation of different compositions, as well as their applications in LIBs is systematically summarized. Particularly, the fine engineering of different pore parameters for Si-based materials is on focus. Importantly, the relationship between thick electrodes and tortuosity/porosity, and the structural effect between pores and battery performance are also discussed in depth. Finally, the applications of porous Si-based anodes in full-cells and their commercial achievements are briefly described. This review is expected to provide a basic understanding and deep insight into developing porous Si-based anodes for high-energy lithium storage. |
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Keywords: | full cell lithium-ion batteries porous structures Si-based anodes synthetic strategies |
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