Characterization of glass-ceramic corrosion and durability

The chemical durability of some selected glass-ceramic materials based on the Li₂O- (MnO, CaO)MgO---Al₂O₃---SiO₂ glass composition, has been determined by HCl, using the powder test.

The leachability of the glass-ceramic was gradually increased by replacing MgO with MnO, while it was decreased by addition of MnO instead of CaO. Calcium oxide had a retarding effect on the durability of the material when it was added instead of MgO and/or MnO. However, on the addition of Al₂O₃ in replacing Li₂O, the durability of the material was markedly improved. The leaching data were found to be dependent mainly on the proportion of the glass oxide constituents i.e. MgO/MnO, CaO/MnO and Li₂O/Al₂O₃ ratios present in the glasses.

The results were correlated to different views concerning the effect of various ions on the rate of interdiffusion between the crystalline-glass materials and leaching solution, the type, and proportions of the crystalline phases developed in glass-ceramics and residual glass phase.