Miscibility and fracture energy of probe tack for acrylic pressure-sensitive adhesives: acrylic copolymer/tackifier resin systems

The relationship between the miscibility of acrylic pressure-sensitive adhesive (PSA) and the fracture energy (W) (Jm⁻²) of the probe tack was investigated, wherein the master curve of W was compared with that of the maximum force (σ_max) (gf) of the probe tack. It was ascertained that W of acrylic PSA was closely related to the miscibility between the components (acrylic copolymer and tackifier resin). In the case of the miscible blend system, the master curve of W shifted toward the lower rate side and, at the same time, the magnitude decreased as the tackifier resin content increased. The degree of the shift of W was extremely smaller than that of σ_max. In the case of the immiscible blend system, the master curve of W remarkably decreased as the tackifier resin content increased, which suggests the fact that W of the PSA depended on the dynamic mechanical properties of the matrix phase and that the resin-rich phase acted as a kind of filler, thus reducing the practical performance. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 581–587, 1998