Optimization of batch solution polymerizations: Simulation studies using an inhibitor and a chain-transfer agent

Multiobjective constrained optimizations are carried out to compute optimal operation policies for batch solution polymerizations of styrene. It is shown by simulations how specified values for conversion, average molecular weight, and polydispersity may be achieved through the proper manipulation of the temperature profile and the initial amounts of the initiator, chain-transfer agent (modifier), and inhibitor. The optimizations show that the use of inhibitors and/or modifiers is seldomly required, unless the process economics is taken into consideration or the high-molecular weight chain fraction of the final polymer resin is to be minimized. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1137–1152, 1998