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碳酸二乙酯黏度和密度的实验测量及数据关联
引用本文:孟现阳,郑平军,吴江涛. 碳酸二乙酯黏度和密度的实验测量及数据关联[J]. 化工学报, 2008, 59(11): 2695-2700
作者姓名:孟现阳  郑平军  吴江涛
作者单位:西安交通大学动力工程多相流国家重点实验室,陕西,西安,710049;西安交通大学动力工程多相流国家重点实验室,陕西,西安,710049;西安交通大学动力工程多相流国家重点实验室,陕西,西安,710049
基金项目:全国优秀博士论文作者专项资金项目,教育部跨世纪优秀人才培养计划
摘    要:采用振动弦黏度/密度计对碳酸二乙酯的黏度与密度进行了实验研究,测量的温度范围为263~363 K,压力范围为0.1~20 MPa。实验系统黏度和密度测量的不确定度分别为±2.0%和±0.2%。利用得到的实验数据,分别拟合了碳酸二乙酯黏度和密度方程。黏度实验数据与方程的平均绝对偏差为0.54%,最大绝对偏差为1.98%;密度实验数据与方程的平均绝对偏差为0.042%,最大绝对偏差为0.12%。最后将实验数据与文献数据进行了比较。为碳酸二乙酯作为替代燃料等研究提供了基础数据。

关 键 词:密度  碳酸二乙酯  振动弦  黏度
收稿时间:2008-03-21
修稿时间:2008-8-5 

Measurements of viscosity and density of diethyl carbonate
MENG Xianyang,ZHENG Pingjun,WU Jiangtao. Measurements of viscosity and density of diethyl carbonate[J]. Journal of Chemical Industry and Engineering(China), 2008, 59(11): 2695-2700
Authors:MENG Xianyang  ZHENG Pingjun  WU Jiangtao
Abstract:Measurements of the viscosity and density of diethyl carbonate are reported at temperatures from 263 K to 363 K and at pressures up to 20 MPa.The measurements were performed simultaneously by using a vibrating-wire instrument operating in the forced mode of oscillation.The overall uncertainties of these results were ±2.0% in viscosity and ±0.2% in density.The measurements were correlated with the Tait-type equation for density and the Hard-sphere scheme for viscosity.The average absolute deviation and the maximum absolute deviation of the viscosity measurements from the correlation for diethyl carbonate were 0.54% and 1.98%, respectively.With regard to density, the average absolute deviation and the maximum absolute deviation of the present results from the correlation were 0.042% and 0.12%, respectively.Comparisons of the experimental data and measurements from literatures with the values calculated by the correlations at different temperatures and pressures were presented.
Keywords:density  diethyl carbonate  vibrating wire  viscosity
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