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一种新颖的含黄酮结构可交联高分子染料的合成与染色性能研究(英文)
引用本文:汤立军,唐炳涛,张淑芬.一种新颖的含黄酮结构可交联高分子染料的合成与染色性能研究(英文)[J].中国化学工程学报,2011,19(4):661-665.
作者姓名:汤立军  唐炳涛  张淑芬
作者单位:1. College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121013, China;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
基金项目:Supported by the National Natural Science Foundation of China (20804007); the State Key Laboratory of Fine Chemicals(KF1014)
摘    要:A yellow crosslinking polymeric dye was prepared by grafting the flavone moiety containing azo chromophore onto polyvinylamine backbone.The λ max of this polymeric dye in water is 382 nm.The polymeric dye is fixed to silk and cotton with a crosslinking agent,2-chloro-4,6-di(aminobenzene-4’-β-sulphatoethylsulphone)-1,3,5-s-triazine,which acts as a bridge between the fiber and dye molecules.The fixation of this polymeric dye reaches 99% and the dyed samples exhibit excellent rubbing and washing fastness.

关 键 词:高分子染料  交联聚合物  染色性能  黄酮类  基团  制备  水洗牢度  聚乙烯胺
收稿时间:2010-2-9
修稿时间:2011-5-16  

Preparation and Dyeing Performance of a Novel Crosslinking Polymeric Dye Containing Flavone Moiety
Lijun TANG,Bingtao TANG,Shufen ZHANG.Preparation and Dyeing Performance of a Novel Crosslinking Polymeric Dye Containing Flavone Moiety[J].Chinese Journal of Chemical Engineering,2011,19(4):661-665.
Authors:Lijun TANG  Bingtao TANG  Shufen ZHANG
Affiliation:1. College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121013, China;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
Abstract:A yellow crosslinking polymeric dye was prepared by grafting the flavone moiety containing azo chromophore onto polyvinylamine backbone. The λmax of this polymeric dye in water is 382 nm. The polymeric dye is fixed to silk and cotton with a crosslinking agent, 2-chloro-4,6-di(aminobenzene-4′-β-sulphatoethylsulphone)-1,3,5-s-triazine, which acts as a bridge between the fiber and dye molecules. The fixation of this polymeric dye reaches 99% and the dyed samples exhibit excellent rubbing and washing fastness.
Keywords:polymeric dye  crosslinking dye  crosslinking agent  flavone
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