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Maskless pendeo-epitaxial growth of GaN films
Authors:Roskowski  A. M.  Preble  E. A.  Einfeldt  S.  Miraglia  P. M.  Davis  R. F.
Affiliation:(1) Department of Chemical Engineering, North Carolina State University, 27695-7919 Raleigh, NC;(2) Department of Materials Science and Engineering, North Carolina State University, USA;(3) Institute of Solid State Physics, University of Bremen, 28334 Bremen, Germany
Abstract:High-resolution x-ray diffraction (XRD) and atomic force microscopy (AFM) of pendeo-epitaxial (PE) GaN films confirmed transmission electron microscopy (TEM) results regarding the reduction in dislocations in the wings. Wing tilt ≤0.15° was due to tensile stresses in the stripes induced by thermal expansion mismatch between the GaN and the SiC substrate. A strong D°X peak at ≈3.466 eV (full-width half-maximum (FWHM) ≤300 μeV) was measured in the wing material. Films grown at 1020°C exhibited similar vertical [0001] and lateral [11 
$$bar 2$$
0] growth rates. Increasing the temperature increased the latter due to the higher thermal stability of the GaN(11 
$$bar 2$$
0). The (11 
$$bar 2$$
0) surface was atomically smooth under all growth conditions with a root mean square (RMS)=0.17 nm.
Keywords:Pendeo-epitaxy (PE)  gallium nitride (GaN)  metalorganic vapor phase epitaxy (MOVPE)  atomic force microscopy (AFM)  x-ray diffraction (XRD)  photoluminescence (PL)
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