Synergetic effect of cyanogen functionalized carbon nanotube and graphene on the mechanical and thermal properties of poly (arylene ether nitrile) |
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Authors: | Xulin Yang Yingqing Zhan Jian Yang Jiachun Zhong Rui Zhao Xiaobo Liu |
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Affiliation: | (1) Research Branch of Functional Materials, Institute of Microelectronic & Solid State Electronic, University of Electronic Science and Technology of China, Chengdu, 610054, People’s Republic of China; |
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Abstract: | Cyanogen functionalized carbon nanotube and graphene/poly (arylene ether nitrile) (CNT-CN/GN-CN/PEN) nanocomposite films were
prepared by a facile solution casting method. The weight ratio of CNT-CN/GN-CN was varied from CNT-dominated to GN-dominated
for the purpose of investigating their synergetic effects on the mechanical and thermal properties of PEN nanocomposites.
Consequently, GN-CN/PEN composites demonstrated better mechanical and thermal properties than CNT-CN/PEN composites due to
larger contact area between GN-CN and PEN matrix. Nevertheless, all CNT-CN/GN-CN/PEN composites exhibit enhanced mechanical
properties than those of GN-only nanocomposites. With the increasing of CNT-CN/GN-CN weight ratio, the mechanical properties
of CNT-CN/GN-CN/PEN composites increase, then decrease, and reach their maximums when CNT-CN/GN-CN weight ratio is around
4/4. From scanning electron microscope images, it is found that around that point GN-CN is flatly dispersed and CNT-CN is
penetrated into GN-CN, capable of transferring stress load and thus decreasing interface loss. Thermal properties of CNT-CN/GN-CN/PEN
composites once again confirmed the joint effect of CNT-CN and GN-CN, leading to improved thermal properties. In short, a
synergistic effect between one-dimensional (1-D) CNT and two-dimensional (2-D) GN on the mechanical and thermal properties
of nanocomposites have been demonstrated in these systems. |
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