Synthesis and Properties of Organosilicon Quaternary Salts Surfactants

Diethyl-benzyl-3-methyldimethoxyl)]silpropyl ammonium chloride (DEBSAC) was synthesized from N,N-diethyl-aminopropyl-methyldimethoxysilane (DEAPMDES) and benzyl chloride. Diethyl-2,3-epoxypropyl-3-methyldimethoxyl)] silpropyl ammonium chloride (DEEPSAC) was synthesized from DEAPMDES and epoxy chloropropane. Trimethyl-3-methyldimethoxyl)] silpropyl ammonium chloride (TMSAC) was synthesized from trimethylamine and γ-chloropropylmethyldimethoxysilane (CPMDMS). The products were characterized by ¹H NMR, ¹³C NMR, and IR. The surface tension measurements showed that the organosilicon quaternary salts exhibit a lower surface tension and a lower critical micelle concentration (CMC) than the hydrocarbon counterparts. The plate count method experiments illustrated that DEEPSAC has a better degree of antibacterial activity against Escherichia coli than DEBSAC. The solubilizing effects of the organosilicon quaternary salts on organosilicone were studied by pseudo-ternary phase diagrams of synthesized products/cosurfactant(n-butanol)/water/octamethylcyclotetrasiloxane. The solubilizing activities decreased in the order of TMSAC > DEBSAC > DEEPSAC.