| 应用溶剂热组合化学方法研究过渡金属对层状磷酸铝化合物[C_6N_4H_(21)][Al_3P_4O_(16)]的影响 |
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| 引用本文： | 宋宇,王永为,李长敏,刘俊龙. 应用溶剂热组合化学方法研究过渡金属对层状磷酸铝化合物[C_6N_4H_(21)][Al_3P_4O_(16)]的影响[J]. 大连工业大学学报, 2007, 26(2) |
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| 作者姓名： | 宋宇 王永为 李长敏 刘俊龙 |
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| 摘 要： | 利用组合化学方法研究了不同过渡金属及用量对化合物[C6N4H21][Al3P4O16]合成的影响.实验结果显示,铁、锌、钴、锰等二价化合物的存在会使三乙烯四胺(TETA)发生异构化,转变为4,(2-乙胺基)二乙基三胺(TREN),从而导致3-D开放骨架磷酸铝[C24N16H91][Al9-xMx(PO4)12].nH2O的生成(M=Zn2+,Mn2+,Fe2+,Co2+).
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| 关 键 词： | 溶剂热 组合化学 层状磷酸铝 |
Influence of transition metal cations on template of the layered aluminophosphate [C6N4H21][Al3P4O16] by applied combinatorial approach |
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| SONG Yu,WANG Yong-wei,LI Chang-min,LIU Jun-long. Influence of transition metal cations on template of the layered aluminophosphate [C6N4H21][Al3P4O16] by applied combinatorial approach[J]. Journal of Dalian Dalian Polytechnic University, 2007, 26(2) |
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| Authors: | SONG Yu WANG Yong-wei LI Chang-min LIU Jun-long |
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| Abstract: | A layered alnminophosphate [C6N4H21][Al3P4O16](compound A) was solventhermally prepared with triethylenetramine(TETA) as the structure-directing agent.When some transitional metal cations was added to the reaction system and TETA was replaced with TREN,3-D open-framework alnminophosphate [C24N16H91][Al9-xMx(PO4)12]·nH2O(M=Zn2+,Mn2+,Fe2+,Co2+) was synthesized. |
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| Keywords: | solventhermally combinatorial approach alnminophosphate |
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