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B2O3与Mg-Li 合金反应合成复合材料的热力学及动力学研究
引用本文:于化顺,闵光辉,任旭芳,陈熙琛. B2O3与Mg-Li 合金反应合成复合材料的热力学及动力学研究[J]. 复合材料学报, 1998, 15(2): 18-22
作者姓名:于化顺  闵光辉  任旭芳  陈熙琛
作者单位:1. 山东工业大学材料学院,济南,250061
2. 中科院物理所,北京,100080
基金项目:山东省自然科学基金,国防重点实验室基金,,,,
摘    要:通过DTA 及液淬试验, 对B2O3与Mg-Li 合金反应合成MgO 颗粒增强Mg-Li 基复合材料的热力学及动力学进行了研究。结果表明,B2O3与Mg-Li 合金的反应温度与Mg-Li 合金常规熔炼温度接近, 且反应速度很快, 适于反应合成复合材料的制备。显微组织观察与XRD 分析发现, 反应生成的MgO 颗粒尺寸细小, 形状圆整且分布均匀。

关 键 词:Mg-Li 基复合材料   反应合成   热力学及动力学

THERMODYNAMICS AND KINETICS OF THE REACTION OF B2O3 WITH Mg-Li ALLOY FOR THE FABRICATION OF Mg-Li COMPOSITES
Yu Huashun,Min Guanghui,Ren Xufang,Chen Xichen. THERMODYNAMICS AND KINETICS OF THE REACTION OF B2O3 WITH Mg-Li ALLOY FOR THE FABRICATION OF Mg-Li COMPOSITES[J]. Acta Materiae Compositae Sinica, 1998, 15(2): 18-22
Authors:Yu Huashun  Min Guanghui  Ren Xufang  Chen Xichen
Affiliation:1. Institute of Material, Shandong University of Technology, Jinan 250061;2. Institute of physics, Chinese Academy of Science, Beijing 100080
Abstract:This paper deals with the thermodynamics and kinetics of the reaction of B2O3 with Mg-Li alloy for the production of MgO particulates reinforced Mg-Li composites, which were examined with DTA and water quenching. It can be seen that the reaction of B2O3 with Mg-Li alloy could take place at the usual melting temperature of Mg-Li alloys and the reaction rate is quick. Fine, spherical and dispersed MgO particulates were formed by reactive synthesis process, and the presence of MgO was verified by XRD data. The mechanism of reaction is also discussed.
Keywords:Mg-Li composites   reactive synthesis process   thermodynamics and kinetics  
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