| 杯[4]芳烃偶氮衍生物的合成及其金属离子萃取性能 |
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| 引用本文： | 吴玉芹.杯[4]芳烃偶氮衍生物的合成及其金属离子萃取性能[J].四川化工,2011(6):1-3. |
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| 作者姓名： | 吴玉芹 |
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| 作者单位： | 江苏盐城工学院,江苏盐城,224051 |
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| 摘 要： | 杯芳烃作为超分子化学的重要组成部分，近年来得到了快速发展并成为化学家的研究热点。以脱叔丁基-杯4]芳烃为原料合成了杯4]芳烃偶氮衍生物，其结构经IR和1H NMR所表征。研究了该主体分子对金属离子的萃取性能，实验结果表明，该主体分子对Mg2＋具有较高的萃取作用。讨论了主客体间配位作用的机制。
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| 关 键 词： | 杯[4]芳烃偶氮衍生物 合成 萃取 Mg2＋ |
Synthesis of Calix[4]arene Azo Derivative and Its Extraction Abilities for Metal Ions |
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| Wu Yuqin.Synthesis of Calix[4]arene Azo Derivative and Its Extraction Abilities for Metal Ions[J].sichuan chemical industry,2011(6):1-3. |
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| Authors: | Wu Yuqin |
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| Affiliation: | Wu Yuqin(Department of Experiment Teaching of Yancheng Institute of Technology,Yancheng 224051,Jiangsu,China) |
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| Abstract: | As an important component of the supermolecular chemistry,the calixarene has developed rapidly and become interest of the chemists.In this paper the calix4]arene azo derivative was synthesized and identified by IR and 1H NMR.The extraction properties of the host molecular for metal ions were studied.The test results showed that the calix4]arene azo derivative has better extraction capabilities with Mg2+.The mechanism of extraction was discussed. |
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| Keywords: | calix[4]arene azo derivative synthesis extraction Mg2 |
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