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AMPS/St/BA三元共聚水稻种衣剂用成膜剂的合成
引用本文:张漫漫,李布青,刘亮,雷震宇,郭肖颖.AMPS/St/BA三元共聚水稻种衣剂用成膜剂的合成[J].化学与粘合,2010,32(3):8-11.
作者姓名:张漫漫  李布青  刘亮  雷震宇  郭肖颖
作者单位:张漫漫,刘亮,雷震宇,ZHANG Man-man,LIU Liang,LEI Zhen-yu(安徽大学生命科学学院,安徽合肥,230039);李布青,郭肖颖,LI Bu-qing,GUO Xiao-ying(安徽省农业科学院农业工程研究所,安徽合肥,230031) 
基金项目:安徽省科技攻关计划,合肥市应用研发项目 
摘    要:采用乳液共聚法,以2-丙烯酰胺-2-甲基丙磺酸(AMPS)为亲水性阴离子单体、苯乙烯(St)和丙烯酸丁酯(BA)为疏水性酯类单体,合成了水稻种衣剂用AMPS/St/BA三元共聚成膜剂。考察了单体、引发剂、复合乳化剂和交联剂对成膜剂性能的影响。结果表明,在AMPS、引发剂和交联剂用量分别是单体量的4%、0.3%和3%,复合乳化剂用量是单体量的3%,且SDS和DNS-458的质量比为1:3时,成膜剂的性能最佳。合成的成膜剂具有良好的耐水性和生物相容性,适用于制备耐水性要求较高的水稻种衣剂。

关 键 词:种衣剂  成膜剂  乳液聚合  2-丙烯酰胺-2-甲基丙磺酸  苯乙烯  丙烯酸丁酯

Synthesis of Film-forming Agent with AMPS/St/BA Copolymer for Rice Seed Coating
ZHANG Man-man,LI Bu-qing,LIU Liang,LEI Zhen-yu,GUO Xiao-ying.Synthesis of Film-forming Agent with AMPS/St/BA Copolymer for Rice Seed Coating[J].Chemistry and Adhesion,2010,32(3):8-11.
Authors:ZHANG Man-man  LI Bu-qing  LIU Liang  LEI Zhen-yu  GUO Xiao-ying
Affiliation:ZHANG Man-man1,LI Bu-qing2,LIU Liang1,LEI Zhen-yu1 and GUO Xiao-ying2(1.College of Life Science,Anhui University,Hefei 230039,China,2.Institute of Agricultural Engineering,Anhui Academy of Agricultural Science,Hefei 230031,China)
Abstract:With using 2-acrylamide-2-methyl-propanesulfonic acid(AMPS) as hydrophilic anionic monomer,and styrene(St) and butyl acrylate(BA) as the hydrophobic monomer,the film-forming agent(namely AMPS/St/BA copolymer) for rice seed coating was synthesized by emulsion copolymerization.The influences of monomers,initiator,composite emulsifier and crosslinking agent on the film-forming agent performance were investigated.The results showed that,when the AMPS,initiator and crosslinking amount was 4%,0.3% and 3% of the m...
Keywords:Rice seed-coating agent  film-forming agent  emulsion polymerization  AMPS  St  BA  
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