Novel iron meso-nitrooctaethylporphine complexes for the catalytic reaction of alkanes with molecular oxygen |
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| Authors: | P. E. Ellis Jr. J. E. Lyons S. N. Shaikh |
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| Affiliation: | (1) Research and Development Department, Sun Company Inc., 19061 Marcus Hook, PA, USA |
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| Abstract: | Introducing nitro groups into themeso-positions of a metalloporphyrin converts a catalytically inactive complex into a highly active catalyst for the oxidation of alkanes with molecular oxygen. The degree of nitration correlates with both the Fe(III)/Fe(II) reduction potential and the catalytic activity. |
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| Keywords: | Metallonitroporphines oxidation isobutane propane |
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