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The NO x reduction mechanism by H2 under near isothermal conditions over Pt–Ba/Al2O3 Lean NO x Trap systems
Authors:Castoldi  L.  Nova  I.  Lietti  L.  Tronconi  E.  Forzatti  P.
Affiliation:(1) Dipartimento Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Centro NEMAS – Nano Engineered MAterials and Surfaces, Politecnico di Milano, p.za Leonardo da Vinci, 32, 20133 Milano, Italy
Abstract:The study of the gas-phase NO reduction by H2 and of the stability/reactivity of NO x stored over Pt–Ba/Al2O3 Lean NO x Trap systems allowed to propose the occurrence of a reduction process of the stored nitrates occurring via to a Pt-catalyzed surface reaction which does not involve, as a preliminary step, the thermal decomposition of the adsorbed NO x species.
Keywords:Lean deNO x   NO x reduction mechanism  LNT systems  Pt–  Ba/Al2O3 catalyst  TPR  TPSR
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