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The relationship between chemical structure and reactivity of alberta bitumens and heavy oils
Authors:M. R. Gray  P. Jokuty  H. Yeniova  L. Nazarewycz  S. E. Wanke  U. Achia  A. Krzywicki  E. C. Sanford  O. K. Y. Sy
Abstract:Long residues (424°C +) from Athabasca, Cold Lake, Lloydminster, and Peace River were hydrocracked over a commercial NilMo on y-alumina catalyst at 430°C, 13.9 MPa (2000 psia). The conversion of residue fraction ranged from 55 to 68%, and was correlated with the concentration of carbon bound to aromatic rings in the feeds. Conversions of sulfur, Micro-Carbon Residue, and metals were all highest for Peace River feed, following the same ranking as residue conversion. Estimates for the breakage of carbon-carbon bonds and the uptake of hydrogen were diagnostic in interpreting the reactor performance.
Keywords:bitumen  hydrocracking  hydrodesulfurization  structural characterization
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