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Measurement and correlation of solubilities ofo- , m- andp-Coumaric Acid isomers in supercritical Carbon Dioxide
Authors:Eun Sun Choi  Hun Yong Shin  Seong-Sik You  Ki-Pung Yoo
Affiliation:(1) Department of Chemical Engineering, Sogang University, C.P.O. Box 1142, Seoul, Korea
Abstract:The solubility of isomerico-, m- and p-coumaric acids in supercritical carbon dioxide were measured by a flow-type experimental apparatus at 308.15-323.15 K and 8.5–25 MPa. The data were modeled by an empirical density-based correlation and a recent EOS formulated by the authors based on approximated lattice-hole theory. We found thatm-coumaric acid showed the highest solubility and o-coumaric acid showed the lowest solubility at the experimental pressures and temperatures.
Keywords:Supercritical Fluid Extraction    Carbon Dioxide    Biosubstances Coumaric Acid homers    Thermodynamic Modeling
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