| 单分散氢氧化钙/聚苯乙烯微球的制备与表征 |
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| 引用本文： | 钟至荣,李红,黄浔. 单分散氢氧化钙/聚苯乙烯微球的制备与表征[J]. 无机盐工业, 2009, 41(8) |
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| 作者姓名： | 钟至荣 李红 黄浔 |
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| 作者单位： | 1. 广东工业大学轻工化工学院,广东广州,510090
2. 中山大学化学与化学工程学院 |
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| 摘 要： | 以葡萄糖水溶液为反应介质,在氧化钙消化成氢氧化钙的过程中,加入苯乙烯单体和引发剂,采用原位悬浮聚合法成功制备了聚苯乙烯(PS)包覆氢氧化钙[Ca(OH)2]形成Ca(OH)2/PS微球.考察了葡萄糖水溶液、苯乙烯、稳定剂聚乙烯醇以及反应温度对单分散Ca(OH)2/PS微球的粒径及粒子分散系数的影响,得出较佳合成条件.在较佳条件下制备的Ca(OH)2/PS微球平均粒径为30～40 μm,粒子分散系数为0.08～0.10.扫描电镜照片表明,Ca(OH)2/PS具有良好的球形度,表面光滑、无破损.红外光谱表征显示,产物为Ca(OH)2/PS微球.
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| 关 键 词： | 氢氧化钙/聚苯乙烯微球 葡萄糖水溶液 原位悬浮聚合 |
Preparation and characterization of monodisperse calcium hydroxide/polystyrene microspheres |
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| Zhong Zhirong,Li Hong,Huang Xun. Preparation and characterization of monodisperse calcium hydroxide/polystyrene microspheres[J]. Inorganic Chemicals Industry, 2009, 41(8) |
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| Authors: | Zhong Zhirong Li Hong Huang Xun |
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| Abstract: | Polystyrene(PS) coated calcium hydroxide[Ca(OH)2],namely Ca(OH)2/PS microspheres were successfully prepared by in-situ suspension polymerization method through adding initiator and styrene monomer into glucose - aqueous media when calcium oxide (CaO) turning into Ca(OH)2.Effects of glucose - aqueous solution,styrene,stabilizer-polyvinyl alcohol (PVA),and reaction temperature on particle size and dispersion coefficient of monodisperse Ca(OH)2/PS microspheres were investigated and optimal synthesis conditions were obtained.Ca(OH)2/PS microspheres with average particle size of 30～40 μm and particle dispersion coefficient of 0.08～0.10 were obtained under optimal conditions.SEM photos showed that Ca(OH)2/PS has good sphericity,smooth surface and no damage.Infrared spectroscopy (FT-IR) indicated that the products were Ca(OH)2/PS microspheres. |
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| Keywords: | Ca(OH)2/PS microspheres glucose - water solution in-situ suspension polymerization |
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