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铈改性分子筛对汽油中噻吩去除效果的研究
引用本文:张洋,王银叶,张晓艳,梁晓芳.铈改性分子筛对汽油中噻吩去除效果的研究[J].天津城市建设学院学报,2009,15(2):117-120.
作者姓名:张洋  王银叶  张晓艳  梁晓芳
作者单位:天津城市建设学院环境与市政工程系,天津,300384
摘    要:以Nax型分子筛为载体,采用浸渍法将Nax型分子筛浸渍到Ce^3+溶液中,利用改性后的分子筛对汽油中噻吩去除的效果进行了试验测试,测试中考察了改性分子筛的用量、吸附时间、初始浓度和搅拌速度对去除噻吩的影响,并且比较了改性前后分子筛吸附量的变化.结果表明:Ce^3+改性分子筛在吸附噻吩1h后达到吸附平衡,最大吸附量为13.1mg/g,且初始浓度越大,搅拌时间越长,越有利于吸附反应的进行;搅拌速度太快,反而不利于对噻吩的吸附.

关 键 词:噻吩  铈改性  NaX型分子筛  吸附

Research on the Removal Effect of Thiophene from Gasoline by Ce-modified Molecular Sieve
ZHANG Yang,WANG Yin-ye,ZHANG Xiao-yan,LIANG Xiao-fang.Research on the Removal Effect of Thiophene from Gasoline by Ce-modified Molecular Sieve[J].Journal of Tianjin Institute of Urban Construction,2009,15(2):117-120.
Authors:ZHANG Yang  WANG Yin-ye  ZHANG Xiao-yan  LIANG Xiao-fang
Affiliation:(Department of Environmental and Municipal Engineering, TIUC, Tianjin 300384, China)
Abstract:NaX-molecular sieve was used as carrier and was dipped into Ce^3+ solution by impregnation. The removal effect of thiophene from gasoline using modified molecular sieve was tested which including the effect of its dosage, adsorption time, initial concentration and mixing speed. The adsorption, before and after the modification of molecular sieve, was compared. Experimental results indicated that the adsorption of Ce-modified molecular sieve to thiophene reached equilibrium after one hour. The largest amount of this absorption is 13.1 mg/g. High initial concentration and long mixing time are good to adsorption reaction but too fast mixing speed goes against the adsorption of thiophene.
Keywords:thiophene  Ce-modified  NaX-molecular sieve  adsorption
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