| 萜烯基聚酯丙烯酸酯的合成及性能研究 |
| |
| 引用本文： | 宋蒙蒙,谢晖,黄莉,赵丽.萜烯基聚酯丙烯酸酯的合成及性能研究[J].热固性树脂,2013(3):1-5. |
| |
| 作者姓名： | 宋蒙蒙 谢晖 黄莉 赵丽 |
| |
| 作者单位： | 南京工业大学化工学院 |
| |
| 摘 要： | 以萜烯马来酸酐(TMA)、DCPD、顺酐(MA)、乙二醇(EG)、丙二醇(PG)、丙烯酸(AA)为主要原料,通过三步法合成了聚酯丙烯酸酯。通过红外光谱分析仪、动态机械分析仪和TG研究了不同原料配比、缩聚反应时间、阻聚剂用量对涂膜性能的影响。结果表明,该光固化涂膜具有良好的力学性能、耐化学性能和耐热性,且固化速度快,可单独作为UV固化的预聚物使用。
|
| 关 键 词： | 萜烯马来酸酐 聚酯丙烯酸酯 合成 紫外光固化 预聚物 |
Study on synthesis and properties of terpene based polyester acrylate |
| |
| SONG Meng-meng,XIE Hui,HUANG Li,ZHAO Li.Study on synthesis and properties of terpene based polyester acrylate[J].Thermosetting Resin,2013(3):1-5. |
| |
| Authors: | SONG Meng-meng XIE Hui HUANG Li ZHAO Li |
| |
| Affiliation: | (College of Chemistry and Chemical Engineering,Nangjing University of Technology,Nangjing 210009,China) |
| |
| Abstract: | The polyester acrylate was obtained by three-step synthesis using terpene maleic anhydride(TMA),DCPD,maleic anhydride(MA),ethylene glycol(EG),propylene glycol(PG),acrylic acid(AA) as main raw materials.The effects of different ratio of raw materials,polycondensation time and polymerization inhibitor amount on the film properties were investigated by infrared spectroscopy,dynamic mechanical analyzer and TG.The results showed that the polyester acrylate UV-cured coating film had good mechanical properties,chemical resistance,heat resistance and fast curing rate.The polyester acrylate could be used alone as the UV curable prepolymer. |
| |
| Keywords: | terpene maleic anhydride polyester acrylate synthesis UV curing prepolymer |
| 本文献已被 CNKI 等数据库收录！ |
|
