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Structure-Property relationships in polyacrylate-poly(urethane-urea) interpenetrating polymer networks
Authors:M. Matsuo  T. K. Kwei  D. Klempner  H. L. Frisch
Abstract:Interpenetrating polymer networks of polyacrylate (A) and poly (urethane-urea) (U) were prepared by mixing lattices of self-curing polyacrylate and urethane-urea prepolymer followed by subsequent curing of each network. The structures of the mixtures were analyzed by the dynamic viscoelasticity and the electron microscopy. It was found that a phase inversion occurred from the “U-phase particles in A-phase matrix” to the “A-phase in U-phase matrix” at A/U ? 30/70 as the U-phase content increases. With increasing A-phase content, tensile strength started to increase and elongation-to-break becomes almost constant after the A-phase formed a continuous phase. This implies that the tensile properties are closely related to the morphological features.
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