Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide,propylene oxide and maleic anhydride

Terpolymerization of carbon dioxide (CO₂) with propylene oxide (PO) and maleic anhydride (MA) was successfully carried out using supported zinc glutarate catalyst. Consequently giving high molecular weight poly(propylene carbonate maleate) (PPCMA) in a very high yield (72.5 g polymer/g catalyst). The resulting terpolymers were fully characterized by FTIR, ¹H NMR, ¹³C NMR, and wide‐angle X‐ray diffraction (WAXD) techniques. NMR measurements showed that PPCMA had an almost alternating structure for the components of carbon dioxide and PO. The influence of molecular weight and MA content on the properties of PPCMA was also investigated. Differential scanning calorimetry (DSC) measurements revealed that the glass transition temperature (T_g) of PPCMA increased with increasing molecular weight. Thermogravimetric analysis (TGA) indicated that PPCMA51 exhibited a very high decomposition temperature (263°C) due to the introduction of the double bond of MA into the backbone of terpolymer. The terpolymers with double bonds can be readily subjected to crosslinking reaction in high temperature to give a slightly crosslinked PPCMA, which exhibit superior thermal stability. Tensile tests also showed that the mechanical properties of PPCMA increased with increasing molecular weight. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008