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脉冲CO色谱法测定铜催化剂的活性表面积
引用本文:刘仲堪. 脉冲CO色谱法测定铜催化剂的活性表面积[J]. 天然气化工, 1995, 20(5): 24-27
作者姓名:刘仲堪
作者单位:化工部西南化工研究院
摘    要:介绍了用CO作吸附质,在室温下脉冲吸附测定铜催化剂中活性铜表面积的方法。试验结果表明,在不同载气中进行CO吸附,所得吸附量略有差异,He载气中测得结果略高于H2载气中测得的结果。结果还表明,本方法重复性好,相对误差在5%以内,可以作为快速评选催化剂的有效方法。

关 键 词:铜催化剂,活性表面积,吸附质,CO

Determination of active surface areas of copper-containing catalysts by pulse CO chromatography
Liu Zhongkan. Determination of active surface areas of copper-containing catalysts by pulse CO chromatography[J]. Natural Gas Chemical Industry, 1995, 20(5): 24-27
Authors:Liu Zhongkan
Abstract:A determination method of active surface areas of copper-containing catalysts by pulse adsorption at an ambient temperature with CO as adsorbate is described in the present paper.The experimental results show that the obtained adsorbances are slightly different when CO adsorption is conducted in various carrier gases. The determined data for He carrier gas is slightly higher than that for H2 carrier gas.The results also show that the method has agood reproductivity and the relative error is within 5%, which can be used as an effective method for fast evaluation and selection of catalysts.
Keywords:copper-containing catalyst  active surface area   adsorbate   CO
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